Browsing by Author "Beezer, A. E."

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The base catalysed hydrolysis of methyl paraben, a test reaction for flow microcalorimeters used for determination of both kinetic and thermodynamic parameters

Olomolaiye, D.; Nicolaides, L.; Orchard, J. A.; Labetoulle, C.; O'Neill, M. A. A.; Mitchell, J. C.; Connor, J. A.; Beezer, A. E.; Kemp, Richard B. (2003-03-24)

The results of an inter/intra-laboratory study into a test and reference reaction for isothermal microcalorimeters, the imidazole catalysed hydrolysis of triacetin, have been reported in a recent paper [Thermochim. Acta ...
Practical and theoretical consideration of flow-through microcalorimetry: Determination of 'thermal volume' and its flow rate dependence

Olomolaiye, D.; Volpe, P. L. O.; O'Neill, M. A. A.; Oliveira, D.; Beezer, A. E.; Kemp, Richard B. (2004-04-08)

The results have recently been reported of a preliminary study into the base catalysed hydrolysis of methyl paraben as a test and reference reaction for flow-through microcalorimeters. The values quoted for the rate constant ...

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