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dc.contributor.author Olomolaiye, D.
dc.contributor.author Volpe, P. L. O.
dc.contributor.author O'Neill, M. A. A.
dc.contributor.author Oliveira, D.
dc.contributor.author Beezer, A. E.
dc.contributor.author Kemp, Richard B.
dc.date.accessioned 2009-09-09T09:08:22Z
dc.date.available 2009-09-09T09:08:22Z
dc.date.issued 2004-04-08
dc.identifier.citation Olomolaiye , D , Volpe , P L O , O'Neill , M A A , Oliveira , D , Beezer , A E & Kemp , R B 2004 , ' Practical and theoretical consideration of flow-through microcalorimetry: Determination of 'thermal volume' and its flow rate dependence ' Thermochimica Acta , vol 413 , no. 1-2 , pp. 1-2 . , 10.1016/j.tca.2003.09.021 en
dc.identifier.issn 1872-762X
dc.identifier.other PURE: 122454
dc.identifier.other dspace: 2160/3022
dc.identifier.uri http://hdl.handle.net/2160/3022
dc.description O'Neill, M. A. A., Beezer, A. E., Kemp, R. B., Olomolaiye, D., Volpe, P. L. O., Oliveira, D. (2004). Practical and theoretical consideration of flow-through microcalorimetry: Determination of 'thermal volume' and its flow rate dependence.   Thermochimica Acta, 413, (1-2), 193-199 en
dc.description.abstract The results have recently been reported of a preliminary study into the base catalysed hydrolysis of methyl paraben as a test and reference reaction for flow-through microcalorimeters. The values quoted for the rate constant and the molar enthalpy change are (3.15±0.11)×10−4 s−1 and −50.5±4.3 kJ mol−1, respectively. The present paper explains the results of further studies of the methyl paraben reaction and also describes some practical and theoretical considerations of flow microcalorimetric experiments. It is shown that experimental design (sample and reference arrangements) has a significant impact upon the derived data. Particular attention is paid to the theoretical range of values for the molar enthalpy change and the rate constant, for reactions that could be studied successfully by flow calorimetry. en
dc.format.extent 2 en
dc.language.iso eng
dc.relation.ispartof Thermochimica Acta en
dc.subject Test and reference reaction en
dc.subject Flow microcalorimetry en
dc.subject Methyl paraben en
dc.subject Rate constant en
dc.title Practical and theoretical consideration of flow-through microcalorimetry: Determination of 'thermal volume' and its flow rate dependence en
dc.type Text en
dc.type.publicationtype Article (Journal) en
dc.identifier.doi http://dx.doi.org/10.1016/j.tca.2003.09.021
dc.contributor.institution Institute of Geography & Earth Sciences en
dc.contributor.institution Institute of Biological, Environmental and Rural Sciences en
dc.description.status Peer reviewed en


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